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Lookup NU author(s): Emeritus Professor Bill Clegg,
Dr Keith Izod,
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The reaction between the lithate [Li(THF)4]-[CH2SiMe2C(SiMe3) 2LiC(SiMe3)2SiMe2CH2] and MnCl2 has given a chloride-bridged high-spin lithium manganate, isolated as Li(THF)2.75(Et2O)0.25(μ-Cl)MnC(SiMe 3)2-SiMe2CH2CH2Me 2Si(Me3Si)2C, shown by an X-ray study to contain three-coordinate planar manganese. The ligand precursor HC(SiMe3)2SiMe2CH2CH 2Me2Si(Me3-Si)2CH reacts with methylcesium to give a compound isolated after recrystallization from benzene as (C6H6)3-CsC(SiMe3) 2SiMe2CH2CH2Me2Si(Me 3Si)2CCs(C6H6)3, in which benzene solvate molecules show a variety of hapticities.
Author(s): Eaborn C, Hitchcock PB, Smith JD, Zhang S, Clegg W, Izod K, O'Shaughnessy P
Publication type: Article
Publication status: Published
ISSN (print): 0276-7333
ISSN (electronic): 1520-6041
Publisher: American Chemical Society
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