Browse by author
Lookup NU author(s): Emeritus Professor Bill CleggORCiD,
Dr Keith Izod,
Full text for this publication is not currently held within this repository. Alternative links are provided below where available.
The reaction between the lithate [Li(THF)4]-[CH2SiMe2C(SiMe3) 2LiC(SiMe3)2SiMe2CH2] and MnCl2 has given a chloride-bridged high-spin lithium manganate, isolated as Li(THF)2.75(Et2O)0.25(μ-Cl)MnC(SiMe 3)2-SiMe2CH2CH2Me 2Si(Me3Si)2C, shown by an X-ray study to contain three-coordinate planar manganese. The ligand precursor HC(SiMe3)2SiMe2CH2CH 2Me2Si(Me3-Si)2CH reacts with methylcesium to give a compound isolated after recrystallization from benzene as (C6H6)3-CsC(SiMe3) 2SiMe2CH2CH2Me2Si(Me 3Si)2CCs(C6H6)3, in which benzene solvate molecules show a variety of hapticities.
Author(s): Eaborn C, Hitchcock PB, Smith JD, Zhang S, Clegg W, Izod K, O'Shaughnessy P
Publication type: Article
Publication status: Published
ISSN (print): 0276-7333
ISSN (electronic): 1520-6041
Publisher: American Chemical Society
Altmetrics provided by Altmetric