Toggle Main Menu Toggle Search

Open Access padlockePrints

The first structurally authenticated Rb-PR3 and Cs-PR3 contacts. Synthesis and crystal structures of [Rb{(Me3Si)2CP(C6H4-2-CH2 NMe2)2}]n and [Cs{(Me3Si)2CP(C6H4-2-CH2 NMe2)2}(toluene)]n

Lookup NU author(s): Dr Keith Izod, Emeritus Professor Bill Clegg, Dr Stephen Liddle

Downloads

Full text for this publication is not currently held within this repository. Alternative links are provided below where available.


Abstract

Metathesis between [Li{([Me3Si]2C)P(C6 H4-2-CH2NMe2)2}] (1) and either RbOR or CsOR (R = 2-ethylhexyl) gives the heavier alkali metal phosphinomethanide complexes [Rb{([Me3Si]2C)P(C6H4-2- CH2-NMe2)2}]n (4) and [Cs{([Me3Si]2C)P(C6H4-2- CH2NMe2)2}-(toluene)]n (5), respectively, after recrystallization. Compounds 4 and 5 represent the first examples of complexes containing a Rb-PR3 or Cs-PR3 bond.


Publication metadata

Author(s): Izod K, Clegg W, Liddle ST

Publication type: Article

Publication status: Published

Journal: Organometallics

Year: 2001

Volume: 20

Issue: 3

Pages: 367-369

ISSN (print): 0276-7333

ISSN (electronic): 1520-6041

Publisher: American Chemical Society

URL: http://dx.doi.org/10.1021/om0008732

DOI: 10.1021/om0008732


Altmetrics

Altmetrics provided by Altmetric


Actions

Find at Newcastle University icon    Link to this publication


Share