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Protonation of a lanthanum phosphide-alkyl occurs at the P-La not the C-La bond: Isolation of a cationic lanthanum alkyl complex

Lookup NU author(s): Dr Keith Izod, Dr Stephen Liddle, Emeritus Professor Bill CleggORCiD

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Abstract

Protonation of the heteroleptic, cyclometalated lanthanum phosphide complex [{(Me3Si)2CH}(C6H4-2-CH 2NMe2)-P]La(THF)[P(C6H4-2-CH 2NMe2){CH(SiMe3)(SiMe2CH 2)}] with [Et3NH][BPh4] yields the cationic alkyllanthanum complex [(THF)4La[P(C6H4-2- CH2NMe2){CH(SiMe3)(SiMe2CH 2)}]][BPh4].

Publication metadata

Author(s): Izod K, Liddle ST, Clegg W

Publication type: Article

Publication status: Published

Journal: Chemical Communications

Year: 2004

Volume: 10

Issue: 15

Pages: 1748-1749

Print publication date: 07/08/2004

Date deposited: 09/07/2010

ISSN (print): 1359-7345

ISSN (electronic): 1364-548X

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/b404188g

DOI: 10.1039/b404188g

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