Dr Simon Doherty
Mark Waugh
Thomas Scanlan
Dr Mark Elsegood
Professor William Clegg
et al. | Migratory insertion and CO substitution reactions of the beta,gamma-unsaturated esters and amides [Fe-2(CO)(5)(mu-PPh2)(mu-eta(1):eta(2)-{NuC(O)CH2}C=CH2}] (Nu = OMe, OEt, OPri,NHPh, NHBut): synthesis and characterisation of acyl-bridged [Fe-2(CO)(4)L-2(mu-PPh2)(mu-C=O{C=CH2}CH2C(O)Nu)](L-2 = dppm, dppe) and alkenyl-bridged [Fe-2(CO)(4){P(Ome)(3)}(2)(mu-eta(1):eta(2)-{NuC(O)CH2}C=CH2)] | 2001 |
|
Dr Simon Doherty
Mark Waugh
Thomas Scanlan
Dr Mark Elsegood
Professor William Clegg
et al. | Migratory insertion and CO substitution reactions of the β,γ-unsaturated esters and amides [Fe2(CO)5(μ-PPh2)μ-η 1:η2-{NuC(O)CH2}C=CH2}] (Nu = OMe, OEt, OPri, NHPh, NHBut): Synthesis and characterisation of acyl-bridged | 2001 |
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Dr Simon Doherty
Mark Waugh
Dr Mark Elsegood
Professor William Clegg
| Migratory Insertion and CO Substitution Reactions of Unsaturated Esters and Amides | 2001 |
|
Dr Simon Doherty
Mark Waugh
Thomas Scanlan
Professor William Clegg
Dr Mark Elsegood
et al. | Regioselective addition of tert-BuN C to the alpha carbon atom of the allenyl ligand in [Fe-2(CO)(6)(mu-PPh2){mu-eta(1):eta(2)(alpha,beta)-(H)C-alpha=C-beta=C gamma H2}]: Formation of [Fe-2(CO)(6)(mu-PPh2){mu-eta(1):eta(1)-(tert-BuN C)C=CCH3}] and [Fe-2(CO)(6)(mu-PPh2)(mu-eta(1):eta(2)-{tert-BuNHC(O)CH2}C=CH2)] via competitive 1,3-hydrogen migration and hydrolysis of the reactive allene-bridged intermediate [Fe-2(CO)(6)(mu-PPh2){mu-eta(1):eta(1)-(tert-BuNC)HC=C=CH2}] | 1999 |
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Dr Simon Doherty
Mark Waugh
Thomas Scanlan
Professor William Clegg
Dr Mark Elsegood
et al. | Regioselective Addition of tert-BuNC to the α Carbon Atom of the Allenyl Ligand in [Fe2(CO)6(μ-PPh2){μ-η1:η2α,β-(H)CαCβCγH2}]: Formation of [Fe2(CO)6(μ-PPh2){μ-η1:η1-(tert-BuNC)CCCH3}] and [Fe2(CO)6(μ-PPh2)(μ-η1:η2-{tert-BuNHC(O)CH2}CCH2)] via Competitive 1,3-Hydrogen Migration and Hydrolysis of the Reactive Allene-Bridged Intermediate [Fe2(CO)6(μ-PPh2){μ-η1:η1-(tert-BuNC)HCCCH2}] | 1999 |
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Dr Simon Doherty
Mark Waugh
Thomas Scanlan
Dr Mark Elsegood
Professor William Clegg
et al. | Regioselective addition of tris(dialkylamino) phosphines to [Fe2(CO)6(μ-PPh2){μ-η 1:η2-(H)C=C=CH2}]: Novel P-C coupling reactions and unusual hydrocarbyl rearrangements | 1999 |
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