Dr Simon Doherty Dr Julian Knight Thomas Scanlan Dr Mark Elsegood Professor William Clegg et al. | Iminophosphines: Synthesis, formation of 2,3-dihydro-1 H-benzo[1,3]azaphosphol-3-ium salts and N-(pyridin-2-yl)-2-diphenylphosphinoylaniline, coordination chemistry and applications in platinum group catalyzed Suzuki coupling reactions and hydrosilylations | 2002 |
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Dr Simon Doherty Mark Waugh Thomas Scanlan Dr Mark Elsegood Professor William Clegg et al. | Migratory insertion and CO substitution reactions of the beta,gamma-unsaturated esters and amides [Fe-2(CO)(5)(mu-PPh2)(mu-eta(1):eta(2)-{NuC(O)CH2}C=CH2}] (Nu = OMe, OEt, OPri,NHPh, NHBut): synthesis and characterisation of acyl-bridged [Fe-2(CO)(4)L-2(mu-PPh2)(mu-C=O{C=CH2}CH2C(O)Nu)](L-2 = dppm, dppe) and alkenyl-bridged [Fe-2(CO)(4){P(Ome)(3)}(2)(mu-eta(1):eta(2)-{NuC(O)CH2}C=CH2)] | 2001 |
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Dr Simon Doherty Mark Waugh Thomas Scanlan Dr Mark Elsegood Professor William Clegg et al. | Migratory insertion and CO substitution reactions of the β,γ-unsaturated esters and amides [Fe2(CO)5(μ-PPh2)μ-η 1:η2-{NuC(O)CH2}C=CH2}] (Nu = OMe, OEt, OPri, NHPh, NHBut): Synthesis and characterisation of acyl-bridged | 2001 |
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Dr Simon Doherty Dr Julian Knight Dr Edward Robins Thomas Scanlan Paul Anthony Champkin et al. | Zirconium-mediated synthesis of a new class of 1,4-bis(diphenylphosphino)-1,3-butadiene-bridged diphosphine, NUPHOS: Highly efficient catalysts for palladium-mediated cross couplings | 2001 |
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Dr Simon Doherty Thomas Scanlan Dr Mark Elsegood Professor William Clegg
| Palladium complexes of C2-, C3-, and C4-bridged bis(phospholyl) ligands: Remarkably active catalysts for the copolymerization of ethylene and carbon monoxide | 1999 |
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Dr Simon Doherty Mark Waugh Thomas Scanlan Professor William Clegg Dr Mark Elsegood et al. | Regioselective addition of tert-BuN C to the alpha carbon atom of the allenyl ligand in [Fe-2(CO)(6)(mu-PPh2){mu-eta(1):eta(2)(alpha,beta)-(H)C-alpha=C-beta=C gamma H2}]: Formation of [Fe-2(CO)(6)(mu-PPh2){mu-eta(1):eta(1)-(tert-BuN C)C=CCH3}] and [Fe-2(CO)(6)(mu-PPh2)(mu-eta(1):eta(2)-{tert-BuNHC(O)CH2}C=CH2)] via competitive 1,3-hydrogen migration and hydrolysis of the reactive allene-bridged intermediate [Fe-2(CO)(6)(mu-PPh2){mu-eta(1):eta(1)-(tert-BuNC)HC=C=CH2}] | 1999 |
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Dr Simon Doherty Mark Waugh Thomas Scanlan Professor William Clegg Dr Mark Elsegood et al. | Regioselective Addition of tert-BuNC to the α Carbon Atom of the Allenyl Ligand in [Fe2(CO)6(μ-PPh2){μ-η1:η2α,β-(H)CαCβCγH2}]: Formation of [Fe2(CO)6(μ-PPh2){μ-η1:η1-(tert-BuNC)CCCH3}] and [Fe2(CO)6(μ-PPh2)(μ-η1:η2-{tert-BuNHC(O)CH2}CCH2)] via Competitive 1,3-Hydrogen Migration and Hydrolysis of the Reactive Allene-Bridged Intermediate [Fe2(CO)6(μ-PPh2){μ-η1:η1-(tert-BuNC)HCCCH2}] | 1999 |
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Dr Simon Doherty Mark Waugh Thomas Scanlan Dr Mark Elsegood Professor William Clegg et al. | Regioselective addition of tris(dialkylamino) phosphines to [Fe2(CO)6(μ-PPh2){μ-η 1:η2-(H)C=C=CH2}]: Novel P-C coupling reactions and unusual hydrocarbyl rearrangements | 1999 |
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